Bis(diphenyldithiocarbamato)nickel(II) Singlet oxygen

Monroe, B.M.; Mrowca, J.J.
J. Phys. Chem. 83, 591-595 (1979)

Reaction: Nickel(II) bis(diphenyldithiocarbamate) + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 6.3 × 10⁹(L mol^-1 s^-1)

Experimental method: Modulated photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1.7 × 10⁴ s^-1; k for indicator = 5.3 × 10⁷ L/(mol·s).

Carlsson, D.J.; Suprunchuk, T.; Wiles, D.M.
Can. J. Chem. 52, 3728-3737 (1974)

Reaction: Nickel(II) bis(diphenyldithiocarbamate) + ¹O₂^* ® products and/or physical quenching
Solvent: i-octane

k = <1.0 × 10⁶(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 4.7 × 10⁴ s^-1; k for indicator = 7.3 × 10⁷ L/(mol·s).