Bis[4-(1,1-dimethylethyl)phenylsalicylato]nickel(II) Singlet oxygen

Hrdlovic, P.; Danecek, J.; Karvas, M.; Durmis, J.
Chem. Zvesti 28, 792-801 (1974)

Reaction: Bis[4-(1,1-dimethylethyl)phenylsalicylato]nickel(II) + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄, 90%, CHCl₃, 10%

k = 1.5 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1.4 × 10³ s^-1; k for indicator = 7 × 10⁷ L/(mol·s).