Bis[2-[(1,1-dimethylethylimino)methyl]phenolato]nickel(II) Singlet oxygen

Wilkinson, F.
Singlet Oxygen, Reactions with Organic Compounds and Polymers, B. Ranby and J.F. Rabek (eds.), John Wiley & Sons, New York, N.Y., 1976, p.27-35

Reaction: Bis[2-[(1,1-dimethylethylimino)methyl]phenolato]nickel(II) + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₆

k = 2.6 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly using indicator
Excitation wavelength: 347 nm

Photosensitizer = Methylene Blue; Indicator = 1,3-Diphenylisobenzofuran.