Bis(diisopropyldithiocarbamato)iron(III) Singlet oxygen

Carlsson, D.J.; Suprunchuk, T.; Wiles, D.M.
Can. J. Chem. 52, 3728-3737 (1974)

Reaction: Iron(III) bis(diisopropyldithiocarbamate) + ¹O₂^* ® products and/or physical quenching
Solvent: Hexadecane

k = 1.2 × 10⁹(L mol^-1 s^-1), T = 298K

Experimental method: Discharge
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Indicator = Rubrene; k for indicator = 7.3 × 10⁷ L/(mol·s); used solvent k_d = 9.0 × 10⁴ s^-1.

Carlsson, D.J.; Suprunchuk, T.; Wiles, D.M.
Can. J. Chem. 52, 3728-3737 (1974)

Reaction: Iron(III) bis(diisopropyldithiocarbamate) + ¹O₂^* ® products and/or physical quenching
Solvent: CH₂Cl₂

k = 4.3 × 10⁹(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 7.3 × 10³ s^-1; k for indicator = 8 × 10⁷ L/(mol·s).

Carlsson, D.J.; Wiles, D.M.
Rubber Chem. Technol. 47, 991-1004 (1974)

Reaction: Iron(III) bis(diisopropyldithiocarbamate) + ¹O₂^* ® products and/or physical quenching
Solvent: CH₂Cl₂

k = 3.9 × 10⁹(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 7.3 × 10³ s^-1; k for indicator = 7.3 × 10⁷ L/(mol·s).

Carlsson, D.J.; Wiles, D.M.
Rubber Chem. Technol. 47, 991-1004 (1974)

Reaction: Iron(III) bis(diisopropyldithiocarbamate) + ¹O₂^* ® products and/or physical quenching
Solvent: i-octane

k = 3.8 × 10⁹(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 4.0 × 10⁴ s^-1; k for indicator = 7.3 × 10⁷ L/(mol·s).

Carlsson, D.J.; Suprunchuk, T.; Wiles, D.M.
J. Polym. Sci., Polym. Lett. Ed. 11, 61-65 (1973)

Reaction: Iron(III) bis(diisopropyldithiocarbamate) + ¹O₂^* ® products and/or physical quenching
Solvent: CH₂Cl₂

k = 3.8 × 10⁹(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 7.3 × 10³ s^-1; k for indicator = 7 × 10⁷ L/(mol·s).