Bis(dibutyldithiocarbamato)copper(II) Singlet oxygen

Furue, H.; Russell, K.E.
Can. J. Chem. 56, 1595-1601 (1978)

Reaction: Copper(II) bis(dibutyldithiocarbamate) + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄, 98%, MeOH, 2%

k = < 5 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly using indicator

Photosensitizer = Methylene Blue; Indicator = 1,3-Diphenylisobenzofuran; no effect for [A] = 5 × 10^-6 mol L^-1.