Bis[2-[(butylimino)methyl]-4-methoxyphenolato]nickel(II) Singlet oxygen

Monroe, B.M.; Mrowca, J.J.
J. Phys. Chem. 83, 591-595 (1979)

Reaction: Bis[2-[(butylimino)methyl]-4-methoxyphenolato]nickel(II) + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 3.4 × 10⁹(L mol^-1 s^-1)

Experimental method: Modulated photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1.7 × 10⁴ s^-1; k for indicator = 5.3 × 10⁷ L/(mol·s).

Carlsson, D.J.; Suprunchuk, T.; Wiles, D.M.
Can. J. Chem. 52, 3728-3737 (1974)

Reaction: Bis[2-[(butylimino)methyl]-4-methoxyphenolato]nickel(II) + ¹O₂^* ® products and/or physical quenching
Solvent: Hexadecane

k = 4.0 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Discharge
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Indicator = Rubrene; k for indicator = 7.3 × 10⁷ L/(mol·s); used solvent k_d = 9.0 × 10⁴ s^-1.

Carlsson, D.J.; Suprunchuk, T.; Wiles, D.M.
Can. J. Chem. 52, 3728-3737 (1974)

Reaction: Bis[2-[(butylimino)methyl]-4-methoxyphenolato]nickel(II) + ¹O₂^* ® products and/or physical quenching
Solvent: CH₂Cl₂

k = 2.0 × 10⁹(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 8 × 10³ s^-1; k for indicator = 7.3 × 10⁷ L/(mol·s).

Carlsson, D.J.; Suprunchuk, T.; Wiles, D.M.
Can. J. Chem. 52, 3728-3737 (1974)

Reaction: Bis[2-[(butylimino)methyl]-4-methoxyphenolato]nickel(II) + ¹O₂^* ® products and/or physical quenching
Solvent: i-octane

k = 2.6 × 10⁹(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 4.7 × 10⁴ s^-1; k for indicator = 7.3 × 10⁷ L/(mol·s).

Carlsson, D.J.; Mendenhall, G.D.; Suprunchuk, T.; Wiles, D.M.
J. Am. Chem. Soc. 94, 8960-8962 (1972)

Reaction: Bis[2-[(butylimino)methyl]-4-methoxyphenolato]nickel(II) + ¹O₂^* ® products and/or physical quenching
Solvent: Hexadecane

k = 2.0 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Discharge
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Indicator = Rubrene; k for indicator = 7 × 10⁷ L/(mol·s); used solvent k_d = 9.0 × 10⁴ s^-1.

Carlsson, D.J.; Mendenhall, G.D.; Suprunchuk, T.; Wiles, D.M.
J. Am. Chem. Soc. 94, 8960-8962 (1972)

Reaction: Bis[2-[(butylimino)methyl]-4-methoxyphenolato]nickel(II) + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Rub + ¹O₂^* ®
Solvent: Isooctane, 94%, Methanol, 3%, Pyridine, 3%

k = 3.5 × 10⁹(L mol^-1 s^-1), T = 298K

Experimental method: Chemical reaction
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Indicator = Rubrene; k for indicator = 7 × 10⁷ L/(mol·s); used solvent k_d = 5.0 × 10⁴ s^-1; ¹O₂* from (PhO)₃PO₃.