Bis(acetylacetonato)nickel(II)
Singlet oxygen
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Bis(acetylacetonato)nickel(II)
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Yang, X.-Z.; Chen, Y.; Dickinson, L.C.; Chien, J.C.W.
Polym. Degrad. Stab. 20, 1-35 (1988)
Reaction: Ni(acac)2 + 1O2* ®
products and/or physical quenching
Reference Reaction: Rub + 1O2* ®
Solvent: Methylene chloride
k = 1.8 × 108(L mol-1 s-1)
Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Derived from steady state measurements using indicator
Excitation wavelength: 520 nm
Photosensitizer = Indicator = Rubrene; used solvent kd = 7.3 × 103 s-1; k for indicator = 7 × 107 L/(mol·s).
[Sensitizer] = 1.6 × 10-6 (mol L-1).
[O2] = air.
Byteva, I.M.; Salokhiddinov, K.I.; Bondarev, S.L.
Russ. J. Phys. Chem. 56, 1056-1059 (1982)
Reaction: Ni(acac)2 + 1O2* ®
products and/or physical quenching
Solvent: CH3COCH3, 95%, H2O, 5%
k = 1.5 × 108(L mol-1 s-1)
Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly
Excitation wavelength: 420 nm
Photosensitizer = Palladium(II) mesoporphyrin IX.
Zweig, A.; Henderson, W.A.,Jr.
J. Polym. Sci., Polym. Chem. Ed. 13, 717-736 (1975)
Reaction: Ni(acac)2 + 1O2* ®
products and/or physical quenching
Solvent: C6H5CH3
k = 3 × 108(L mol-1 s-1)
Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator
Photosensitizer = Indicator = Rubrene; used solvent kd = 1 × 105 s-1; k for indicator = 1.7 × 108 L/(mol·s).
Hrdlovic, P.; Danecek, J.; Karvas, M.; Durmis, J.
Chem. Zvesti 28, 792-801 (1974)
Reaction: Ni(acac)2 + 1O2* ®
products and/or physical quenching
Solvent: CCl4, 90%, CHCl3, 10%
k = 8.2 × 107(L mol-1 s-1)
Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Derived from steady state measurements using indicator
Photosensitizer = Indicator = Rubrene; used solvent kd = 1.4 × 103 s-1; k for indicator = 7 × 107 L/(mol·s);
Carlsson, D.J.; Suprunchuk, T.; Wiles, D.M.
Can. J. Chem. 52, 3728-3737 (1974)
Reaction: Ni(acac)2 + 1O2* ®
products and/or physical quenching
Solvent: CH2Cl2
k = 1.5 × 108(L mol-1 s-1), T = 298K
Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator
Photosensitizer = Indicator = Rubrene; used solvent kd = 8 × 103 s-1; k for indicator = 8 × 107 L/(mol·s).
Guillory, J.P.; Cook, C.F.
J. Polym. Sci., Polym. Chem. Ed. 11, 1927-1937 (1973)
Reaction: Ni(acac)2 + 1O2* ®
products and/or physical quenching
Solvent: C6H5Br
k = 6.5 × 107(L mol-1 s-1), T = 273K
Experimental method: Discharge
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator
Indicator = Rubrene; k for indicator = 4.0 × 107 L/(mol·s); used solvent kd = 1.3 × 104 s-1; nickel complex exists as a trimer in solution.
Carlsson, D.J.; Suprunchuk, T.; Wiles, D.M.
J. Polym. Sci., Polym. Lett. Ed. 11, 61-65 (1973)
Reaction: Ni(acac)2 + 1O2* ®
products and/or physical quenching
Solvent: CH2Cl2
k = 7.5 × 107(L mol-1 s-1)
Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator
Photosensitizer = Indicator = Rubrene; used solvent kd = 7.3 × 103 s-1; k for indicator = 7 × 107 L/(mol·s).
Carlsson, D.J.; Mendenhall, G.D.; Suprunchuk, T.; Wiles, D.M.
J. Am. Chem. Soc. 94, 8960-8962 (1972)
Reaction: Ni(acac)2 + 1O2* ®
products and/or physical quenching
Solvent: 2-Butoxyethanol
k = 7.5 × 107(L mol-1 s-1), T = 273K
Experimental method: Discharge
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator
Indicator = Rubrene; k for indicator = 7 × 107 L/(mol·s). used solvent kd = 3.8 × 105 s-1.