1-(Phenylazo)-1-(phenylaminocarbonyl)-2-propanone
Singlet oxygen
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1-(Phenylazo)-1-(phenylaminocarbonyl)-2-propanone
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Koval'chuk, N.V.; Anisimov, V.M.; Tambieva, O.A.; Titov, V.V.
J. Org. Chem. USSR 22, 1746-1753 (1986)
Reaction: 1-(Phenylazo)-1-(phenylaminocarbonyl)-2-propanone + 1O2* ®
products
Reference Reaction: 9,10-Dimethylanthracene + 1O2* ®
Solvent: DMAA
kreact = 3.0 × 105(L mol-1 s-1), kreference = 1.4 × 107(L mol-1 s-1)
Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method
Excitation wavelength: 365 nm
Photosensitizer = Rose Bengal dianion.
Koval'chuk, N.V.; Anisimov, V.M.; Tambieva, O.A.; Titov, V.V.
J. Org. Chem. USSR 22, 1746-1753 (1986)
Reaction: 1-(Phenylazo)-1-(phenylaminocarbonyl)-2-propanone + 1O2* ®
products
Reference Reaction: 9,10-Dimethylanthracene + 1O2* ®
Solvent: DMF
kreact = 1.0 × 105(L mol-1 s-1), kreference = 1.4 × 107(L mol-1 s-1)
Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method
Excitation wavelength: 365 nm
Photosensitizer = Rose Bengal dianion.
Koval'chuk, N.V.; Anisimov, V.M.; Tambieva, O.A.; Titov, V.V.
J. Org. Chem. USSR 22, 1746-1753 (1986)
Reaction: 1-(Phenylazo)-1-(phenylaminocarbonyl)-2-propanone + 1O2* ®
products
Reference Reaction: 9,10-Dimethylanthracene + 1O2* ®
Solvent: 2-PrOH
kreact = 3.2 × 106(L mol-1 s-1), kreference = 1.4 × 107(L mol-1 s-1)
Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method
Excitation wavelength: 365 nm
Photosensitizer = Rose Bengal dianion.