1-(4-Methylphenylazo)-1-(phenylaminocarbonyl)-2-propanone Singlet oxygen

Koval'chuk, N.V.; Anisimov, V.M.; Tambieva, O.A.; Titov, V.V.
J. Org. Chem. USSR 22, 1746-1753 (1986)

Reaction: 1-(4-Methylphenylazo)-1-(phenylaminocarbonyl)-2-propanone + ¹O₂^* ® products
Reference Reaction: 9,10-Dimethylanthracene + ¹O₂^* ®
Solvent: DMAA

k_react = 4.0 × 10⁶(L mol^-1 s^-1), k_reference = 1.4 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method
Excitation wavelength: 365 nm

Photosensitizer = Rose Bengal dianion.

Koval'chuk, N.V.; Anisimov, V.M.; Tambieva, O.A.; Titov, V.V.
J. Org. Chem. USSR 22, 1746-1753 (1986)

Reaction: 1-(4-Methylphenylazo)-1-(phenylaminocarbonyl)-2-propanone + ¹O₂^* ® products
Reference Reaction: 9,10-Dimethylanthracene + ¹O₂^* ®
Solvent: DMF

k_react = 3.0 × 10⁶(L mol^-1 s^-1), k_reference = 1.4 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method
Excitation wavelength: 365 nm

Photosensitizer = Rose Bengal dianion.