Decay constant for singlet oxygen in the solvent:

Methanol-d


Studer, S.L.; Brewer, W.E.; Martinez, M.L.; Chou, P.-T.
J. Am. Chem. Soc. 111(19): 7643-4 (1989)

Lifetime is 2.5 x 10–4 s
Decay rate is 4.1 x 103 s–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is RB or H2TPPS4–.


Chacon, J.N.; McLearie, J.; Sinclair, R.S.
Photochem. Photobiol. 47(5): 647-56 (1988)

Lifetime is 2.9 x 10–5 s
Decay rate is 3.4 x 104 s–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is MB and RF.


Land, E.J.; McDonagh, A.F.; McGarvey, D.J.; Truscott, T.G.
Proc. Natl. Acad. Sci. U.S.A. 85(14): 5249-53 (1988)

Lifetime is 2.8 x 10–5 s
Decay rate is 3.6 x 104 s–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is SnPPCl2.


Redmond, R.W.; Braslavsky, S.E.
NATO ASI Ser., Ser. H 15(Photosensitisation): 93-5 (1988)

Lifetime is 3.2 x 10–5 s
Decay rate is 3.1 x 104 s–1

Experimental method: pulsed laser photolysis, thermal buildup
Sensitizer is HP.


Fuke, K.; Ueda, M.; Itoh, M.
J. Am. Chem. Soc. 105(5): 1091-6 (1983)

Lifetime is 4.0 x 10–5 s
Decay rate is 2.5 x 104 s–1

Experimental method: pulsed laser photolysis, thermal buildup
Sensitizer is Ery.


Manring, L.E.; Foote, C.S.
J. Am. Chem. Soc. 105(14): 4710-7 (1983)

Lifetime is 2.5 x 10–5 s
Decay rate is 4.1 x 104 s–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is MPDME.


Hurst, J.R.; McDonald, J.D.; Schuster, G.B.
J. Am. Chem. Soc. 104(7): 2065-7 (1982)

Lifetime is 3.7 x 10–5 s
Decay rate is 2.7 x 104 s–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is MB.


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