Decay constant for singlet oxygen in the solvent:

Cyclohexane-d12


Chou, P.-T.; Frei, H.
J. Chem. Phys. 87(7): 3843-54 (1987)

Lifetime is 4.5 x 10–4 s
Decay rate is 2.2 x 103 s–1

Experimental method: pulsed laser photolysis, luminescence decay
Sensitizer is Chr
from high intensity photolysis; M = 1O2*.


Jenny, T.A.; Turro, N.J.
Tetrahedron Lett. 23(29): 2923-6 (1982)

Lifetime is 3.2 x 10–4 s
Decay rate is 3.1 x 103 s–1

Experimental method: continuous photolysis, luminescence intensity
Sensitizer is Benz[de]anthracen-7-one, phenalenone or fluorenone
rel. to kd = 4.0 x 104 s–1 in benzene.


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