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Rate Constants for Reactions of Peroxyl Radicals in Fluid Solution

Pedatsur Neta and Robert E. Huie
Chemical Kinetics Division,
National Institute of Standards and Technology,
Gaithersburg, MD 20899

and

Alberta B. Ross
Radiation Chemistry Data Center,
Radiation Laboratory,
University of Notre Dame,
Notre Dame, IN 46556

J. Phys. Chem. Ref. Data 19: 413-513 (1990)

Absolute rate constants for reactions of alkylperoxyl and substituted alkylperoxyl radicals with inorganic and organic compounds in aqueous and non-aqueous fluid solutions have been compiled. The radicals were generated by radiolysis or photolysis and their rate constants were determined generally by kinetic spectrophotometry or esr. Rate constants are included also for formation of peroxyl radicals by reaction of alkyl radicals with oxygen and for decay of peroxyl radicals by radical-radical reactions.

These data have not been arranged for browsing, but may be searched by the name of either of the reactants.