Reduction Potentials

(SCN)₂•^–/2 SCN^–

E = 1330(mV)
Recommended value.

Nord, G.; Pedersen, B.; Farver, O.
Inorg. Chem. 17(8): 2233-8 (1978)

E = 1310(mV), ionic strength = 1, pH = ~1.3

Reference compound: Fe(bpy)₃³⁺
Reference E: 1065 mV

Kinetics + calcn. (rate const. assumed).

Nord, G.; Pedersen, B.; Farver, O.
Inorg. Chem. 17(8): 2233-8 (1978)

E = 1370(mV), ionic strength = 1, pH = ~1.3

Reference compound: Os(bpy)₃³⁺
Reference E: 837 mV

Kinetics + calcn. (some assumptions).

Stanbury, D.M.; Wilmarth, W.K.; Khalaf, S.; Po, H.N.; Byrd, J.E.
Inorg. Chem. 19(9): 2715-22 (1980)

E = 1290(mV)

Reference compound: 9.55
Reference E: 1660 mV

Calcn.

Butler, J.; Land, E.J.; Pruetz, W.A.; Swallow, A.J.
Biochim. Biophys. Acta 705(2): 150-62 (1982)

E = 1250(mV)

Reference compound: 9.29
Reference E: 1000 mV

Calcn.; +- 220 mV.

Nord, G.; Pedersen, B.; Floryan-Lovborg, E.; Pagsberg, P.
Inorg. Chem. 21(6): 2327-30 (1982)

E = 1331(mV), ionic strength = 0.1, pH = ~3

Reference compound: Os(bpy)₃³⁺
Reference E: 857 mV

Kinetics; +- 8 mV.

Schwarz, H.A.; Bielski, B.H.J.
J. Phys. Chem. 90(7): 1445-8 (1986)

E = 1310(mV)

Calcn.

Merenyi, G.; Lind, J.; Shen, X.
J. Phys. Chem. 92(1): 134-7 (1988)

E = 1350(mV)

Reference compound: 6.2.9
Reference E: 1240 mV

Calcn.