Reduction Potentials

I₂•^–/2 I^–

Haim, A.; Taube, H.
J. Am. Chem. Soc. 85(5): 495-500 (1963)

E = 1040(mV)

Calcn.; no details.

Malone, S.D.; Endicott, J.F.
J. Phys. Chem. 76(16): 2223-9 (1972)

E = 1100(mV)

Calcn.

Thornton, A.T.; Laurence, G.S.
J. Chem. Soc., Dalton Trans. (16): 1632-6 (1973)

E = 1000(mV)

Calcn.; +- 50 mV.

Woodruff, W.H.; Margerum, D.W.
Inorg. Chem. 12(4): 962-4 (1973)

E = 1130(mV)

Calcn.

Nord, G.; Pedersen, B.; Farver, O.
Inorg. Chem. 17(8): 2233-8 (1978)

E = 1080(mV), ionic strength = 1, pH = ~1.3

Reference compound: Os(bpy)₃³⁺
Reference E: 840 mV

Kinetics + calcn.

Henglein, A.
Radiat. Phys. Chem. 15(2/3): 151-8 (1980)

E = 1000(mV)

Calcn.

Stanbury, D.M.; Wilmarth, W.K.; Khalaf, S.; Po, H.N.; Byrd, J.E.
Inorg. Chem. 19(9): 2715-22 (1980)

E = 1040(mV)

Reference compound: 9.25
Reference E: 1330 mV

Calcn.

Nord, G.; Pedersen, B.; Floryan-Lovborg, E.; Pagsberg, P.
Inorg. Chem. 21(6): 2327-30 (1982)

E = 1063(mV), ionic strength = 0.1, pH = ~3

Reference compound: Os(bpy)₃³⁺
Reference E: 857 mV

Kinetics; +- 11 mV.

Bahnemann, D.; Asmus, K.-D.; Willson, R.L.
J. Chem. Soc., Perkin Trans. 2 (11): 1669-73 (1983)

E = 981(mV), ionic strength = ~0.1, pH = ~3.5

Reference compound: 7.4.6
Reference E: 865 mV

Concentrations used to estimate equilibrium constant + Kinetics used to estimate equilibrium constant.

Surdhar, P.S.; Armstrong, D.A.
J. Phys. Chem. 90(22): 5915-7 (1986)

E = 1130(mV)

Calcn.

Schwarz, H.A.; Bielski, B.H.J.
J. Phys. Chem. 90(7): 1445-8 (1986)

E = 1030(mV)

Reference compound: 9.41
Reference E: –330 mV

HO₂•/I₂ reaction; Concentrations used to estimate equilibrium constant + Kinetics used to estimate equilibrium constant + calcn.