Reduction Potentials

Phenol
(PhOH)

Steenken, S.; Neta, P.
J. Phys. Chem. 83(9): 1134-7 (1979)

E > 500(mV), ionic strength = 0.5, pH = 13.5
Questionable or superseded value.

Reference compound: 5.3.1
Reference E: 300 mV
Co-solute: glycol

Concentrations used to estimate equilibrium constant, ref. pot. later revised

Steenken, S.; Neta, P.
J. Phys. Chem. 86(18): 3661-7 (1982)

E > 600(mV), ionic strength = 0.5, pH = 13.5 E > 800(mV), pH = 7

Reference compound: 5.3.1
Reference E: 385 mV
Co-solute: glycol

Concentrations used to estimate equilibrium constant; calc.

Huie, R.E.; Neta, P.
J. Phys. Chem. 88(23): 5665-9 (1984)

E = 700(mV), pH = 11.1

Reference compound: SO₃•^–
Reference E: 630 mV

Concentrations used to estimate equilibrium constant + Kinetics used to estimate equilibrium constant; 900 mV calc. for pH 7.

Harriman, A.
J. Phys. Chem. 91(24): 6102-4 (1987)

E = 860(mV), pH = 7

Cyc. v., not E⁰.

Merenyi, G.; Lind, J.; Shen, X.
J. Phys. Chem. 92(1): 134-7 (1988)

E = 800(mV), pH = 13

Reference compound: ClO₂
Reference E: 936 mV

Surdhar, P.S.; Armstrong, D.A.
J. Phys. Chem. 91(26): 6532-7 (1987)

E = 1352(mV), ionic strength = -> 0, pH = (6.0)

Reference compound: 7.5.1
Reference E: 830 mV

Concentrations used to estimate equilibrium constant.

Surdhar, P.S.; Armstrong, D.A.
J. Phys. Chem. 91(26): 6532-7 (1987)

E = 1340(mV)

Calcn.

Surdhar, P.S.; Armstrong, D.A.
J. Phys. Chem. 91(26): 6532-7 (1987)

E = 1340(mV)

Calcn. from data in 84A327