Reduction Potentials

6,7,8,9-Tetrahydro-2,3,12,13-tetramethyldipyrido[1,2-a:2',1'-c][1,4]diazocinediium

(R² = R³ = R¹² = R¹³ = CH₃)

Anderson, R.F.; Patel, K.B.
J. Chem. Soc., Faraday Trans. 1 80(10): 2693-702 (1984)

E = –832(mV), ionic strength = -> 0, pH = 7

Reference E: –613 mV
Co-solute: t-BuOH

Concentrations used to estimate equilibrium constant; Br^– salt.