Reduction Potentials

7,8-Dihydro-2,3,11,12-tetramethyldipyrido[1,2-a:2',1'-c][1,4]diazepinediium

(R² = R³ = R¹¹ = R¹² = CH₃)

Launikonis, A.; Loder, J.W.; Mau, A.W.-H.; Sasse, W.H.F.; Summers, L.A.; Wells, D.
Aust. J. Chem. 35(7): 1341-55 (1982)

E = –770(mV)

Approx. (Value from cyc. v. in CH₃CN taken, less 30 mV.) ClO₄^– salt.

Anderson, R.F.; Patel, K.B.
J. Chem. Soc., Faraday Trans. 1 80(10): 2693-702 (1984)

E = –775(mV), ionic strength = -> 0, pH = 7

Reference compound: 2.4.39
Reference E: –583 mV

Concentrations used to estimate equilibrium constant; Br^– salt.

Anderson, R.F.; Patel, K.B.
J. Chem. Soc., Faraday Trans. 1 80(10): 2693-702 (1984)

E = –778(mV), ionic strength = -> 0, pH = 7

Reference compound: 3.3.17
Reference E: –613 mV

Concentrations used to estimate equilibrium constant; Br^– salt.