Reduction Potentials

Misonidazole

(R¹ = CH₂CH(OH)CH₂OCH₃)

E = –389(mV)
Recommended value.

Meisel, D.; Neta, P.
J. Am. Chem. Soc. 97(18): 5198-203 (1975)

E = –363(mV), ionic strength = ~0.010, pH = 7

Reference compound: DQ
Reference E: –235 mV
Co-solute: 2-PrOH

Concentrations used to estimate equilibrium constant.

Meisel, D.; Neta, P.
J. Am. Chem. Soc. 97(18): 5198-203 (1975)

E = –398(mV), ionic strength = ~0.010, pH = 7

Reference compound: AQS^–
Reference E: –380 mV
Co-solute: 2-PrOH

Concentrations used to estimate equilibrium constant.

Wardman, P.; Clarke, E.D.
J. Chem. Soc., Faraday Trans. 1 72(6): 1377-90 (1976)

E = –389(mV), ionic strength = -> 0, pH = 7

Reference compound: AQS^–
Reference E: –375 mV
Co-solute: 2-PrOH

Concentrations used to estimate equilibrium constant.

Wardman, P.; Clarke, E.D.
J. Chem. Soc., Faraday Trans. 1 72(6): 1377-90 (1976)

E = –389(mV), ionic strength = -> 0, pH = 7

Reference compound: AQS^–
Reference E: –375 mV
Co-solute: t-BuOH

Concentrations used to estimate equilibrium constant (Kinetics used to estimate equilibrium constant)

Wardman, P.; Clarke, E.D.
J. Chem. Soc., Faraday Trans. 1 72(6): 1377-90 (1976)

E = –389(mV), ionic strength = -> 0, pH = 7

Reference compound: AQS^–
Reference E: –375 mV
Co-solute: HCO₂^–

Concentrations used to estimate equilibrium constant, Calculated by the present author from data in reference shown.

Wardman, P.; Clarke, E.D.
J. Chem. Soc., Faraday Trans. 1 72(6): 1377-90 (1976)

E = –388(mV), ionic strength = -> 0, pH = 7

Reference compound: BV²⁺
Reference E: –354 mV
Co-solute: 2-PrOH

Concentrations used to estimate equilibrium constant (Kinetics used to estimate equilibrium constant)