4,7-Diphenyl-1,10-phenanthroline(2,3-naphthalenediolato)platinium(II) Pt(4,7-Ph2phen)(dnt)

Kamath, S.S.; Shukla, S.; Srivastava, T.S.
Bull. Chem. Soc. Jpn. 64(4): 1351-8 (1991)

Sensitizer: 4,7-Diphenyl-1,10-phenanthroline(2,3-naphthalenediolato)platinium(II) Pt(4,7-Ph2phen)(dnt)
Solvent: DMF
Oxygen concentration: O2

Experimental method: continuous photolysis
Data type: product appearance under steady-state conditions

Reference sensitizer = Pd(4,7-Ph2phen)(dhn); Singlet oxygen acceptor = TEMP-4-OH; Product from substrate = 4-Hydroxy-2,2,6,6-tetramethylpiperidine N-oxyl; meas. phiDelta(S)/phiDelta(ref. sens.) = 0.63. Obs. P by esr

back...