4-tert-Butylcatechol(1,10-phenanthroline)palladium(II) Pd(phen)(BCAT)

Shukla, S.; Kamath, S.S.; Srivastava, T.S.
J. Photochem. Photobiol., A 47(3): 287-98 (1989)

Sensitizer: 4-tert-Butylcatechol(1,10-phenanthroline)palladium(II) Pd(phen)(BCAT)
Solvent: DMF
Oxygen concentration: O2

Quantum yield of formation = ~0.18

Experimental method: continuous photolysis
Data type: product appearance under steady-state conditions

Reference sensitizer = Pt(phen)(BCAT); Singlet oxygen acceptor = TEMP-4-OH; Product from substrate = 4-Hydroxy-2,2,6,6-tetramethylpiperidine N-oxyl; rel. to phiDelta(ref. sens.) = ~0.15b. Obs. P by esr.

b Value of phiDelta(S') used in this work to calculate phiDelta(S) from authors'reported phiDelta(S)/phiDelta(S').
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