Benzo[d]naphtho[1,2-b]pyran-6-one, 4-(6-deoxy-alpha-galactofuranosyl)-1-hydroxy-10,12-dimethoxy-8-methyl- (Gilvocarcin V)


Alegria, A.E.; Krishna, C.M.; Elespuru, R.K.; Riesz, P.
Photochem. Photobiol. 49(3): 257-65 (1989)

Sensitizer: Benzo[d]naphtho[1,2-b]pyran-6-one, 4-(6-deoxy-alpha-galactofuranosyl)-1-hydroxy-10,12-dimethoxy-8-methyl- (Gilvocarcin V)
Solvent: DMSO
Oxygen concentration: air

Quantum yield of formation = 0.15

Experimental method: continuous photolysis
Data type: product appearance under steady-state conditions

Reference sensitizer = RB; Singlet oxygen acceptor = TEMP-4-OH; Product from substrate = 4-Hydroxy-2,2,6,6-tetramethylpiperidine N-oxyl; rel. to phiDelta(ref. sens.) = 0.76; lambdaexc = 405 nm.


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