3-Phorbinepropanoic acid, [3,7,11,15-tetramethyl-2-hexadecenyl 3,4-didehydro-9-ethenyl- 14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-3-phorbinepropanoatomagnesium (Protochlorophyll)

Egorov, S.Yu.; Krasnovsky, A.A.,Jr.; Safronova, I.A.; Bystrova, M.I.; Krasnovsky, A.A.
Dokl. Biophys. 299(5): 67-71 (1988)

Sensitizer: 3-Phorbinepropanoic acid, [3,7,11,15-tetramethyl-2-hexadecenyl 3,4-didehydro-9-ethenyl- 14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-3-phorbinepropanoatomagnesium (Protochlorophyll)
Solvent: (C2H5)2O
Oxygen concentration: aira

Quantum yield of formation = 0.84

Experimental method: pulsed laser photolysis
Data type: luminescence intensity at end-of-pulse or under steady-state conditions

Reference sensitizer = TPP; rel. to phiDelta(ref. sens.) = 0.70.

Dzhagarov, B.M.; Sarin, E.I.; Ganzha, V.A.; Gurinovich, G.P.
Khim. Fiz. 6(7): 919-28 (1987)

Sensitizer: 3-Phorbinepropanoic acid, [3,7,11,15-tetramethyl-2-hexadecenyl 3,4-didehydro-9-ethenyl- 14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-3-phorbinepropanoatomagnesium (Protochlorophyll)
Solvent: C6H5CH3
Oxygen concentration: aira

Quantum yield of formation = 0.68

Experimental method: pulsed laser photolysis
Data type: luminescence intensity at end-of-pulse or under steady-state conditions

Reference sensitizer = PdMPDME; rel. to phiDelta(ref. sens.) = 1; lambdaexc = 347 nm.

Krasnovsky, A.A.,Jr.
Photochem. Photobiol. 29(1): 29-36 (1979)

Sensitizer: 3-Phorbinepropanoic acid, [3,7,11,15-tetramethyl-2-hexadecenyl 3,4-didehydro-9-ethenyl- 14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-3-phorbinepropanoatomagnesium (Protochlorophyll)
Solvent: CCl4
Oxygen concentration: air

Quantum yield of formation = 0.63

Experimental method: modulated photolysis
Data type: luminescence intensity at end-of-pulse or under steady-state conditions

Reference sensitizer = Chl a; rel. to phiDelta(ref. sens.) = 0.55. Proportion of T1 quenched by O2 = 1.

Dzhagarov, B.M.; Sarin, E.I.; Ganzha, V.A.; Gurinovich, G.P.
Khim. Fiz. 6(7): 919-28 (1987)

Sensitizer: 3-Phorbinepropanoic acid, [3,7,11,15-tetramethyl-2-hexadecenyl 3,4-didehydro-9-ethenyl- 14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-3-phorbinepropanoatomagnesium (Protochlorophyll)
Solvent: CH3CN
Oxygen concentration: aira

Quantum yield of formation = 0.78

Experimental method: pulsed laser photolysis
Data type: luminescence intensity at end-of-pulse or under steady-state conditions

Reference sensitizer = PdMPDME; rel. to phiDelta(ref. sens.) = 1; lambdaexc = 347 nm.

Egorov, S.Yu.; Krasnovsky, A.A.,Jr.; Safronova, I.A.; Bystrova, M.I.; Krasnovsky, A.A.
Dokl. Biophys. 299(5): 67-71 (1988)

Sensitizer: 3-Phorbinepropanoic acid, [3,7,11,15-tetramethyl-2-hexadecenyl 3,4-didehydro-9-ethenyl- 14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-3-phorbinepropanoatomagnesium (Protochlorophyll)
Solvent: D2O
Oxygen concentration: aira

Quantum yield of formation <=0.02

Experimental method: pulsed laser photolysis
Data type: luminescence intensity at end-of-pulse or under steady-state conditions

Reference sensitizer = H2TPPS4–; rel. to phiDelta(ref. sens.) = 0.70. Colloidal soln. contg. 0.5% NH4OH.

Egorov, S.Yu.; Krasnovsky, A.A.,Jr.; Safronova, I.A.; Bystrova, M.I.; Krasnovsky, A.A.
Dokl. Biophys. 299(5): 67-71 (1988)

Sensitizer: 3-Phorbinepropanoic acid, [3,7,11,15-tetramethyl-2-hexadecenyl 3,4-didehydro-9-ethenyl- 14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-3-phorbinepropanoatomagnesium (Protochlorophyll)
Solvent: D2O (mic)
Oxygen concentration: aira

Quantum yield of formation = 0.84

Experimental method: pulsed laser photolysis
Data type: luminescence intensity at end-of-pulse or under steady-state conditions

Reference sensitizer = H2TPPS4–; rel. to phiDelta(ref. sens.) = 0.70. Soln. cont. 1% Triton X-100.

a Oxygen concentration not given; assumed to be air saturated.
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