Benz[a]anthracene

Darmanyan, A.P.
Chem. Phys. Lett. 96(3): 383-9 (1983)

Sensitizer: Benz[a]anthracene
Solvent: C6H5CH3
Oxygen concentration: 1.2 x 10-3

Experimental method: pulsed laser photolysis
Data type: time resolved substrate disappearance; sensitizer triplet absorbance at end-of-pulse

Singlet oxygen acceptor = Rub; meas. phiT(S) = 0.85; lambdaexc = 347 nm. Proportion of T1 quenched by O2 = 1; used epsilonT(S) = 15,000 L mol-1 cm-1 at lambdamax; nDelta = 0.95.

Gurinovich, G.P.; Salokhiddinov, K.I.
Chem. Phys. Lett. 85(1): 9-11 (1982)

Sensitizer: Benz[a]anthracene
Solvent: C6H5CH3
Oxygen concentration: 1.2 x 10-3

Quantum yield of formation = 1.4

Experimental method: pulsed laser photolysis
Data type: luminescence intensity at end-of-pulse or under steady-state conditions

Reference sensitizer = PdMPDME; rel. to phiDelta(ref. sens.) = 1.0; lambdaexc = 347 nm.

Darmanyan, A.P.
Chem. Phys. Lett. 96(3): 383-9 (1983)

Sensitizer: Benz[a]anthracene
Solvent: C6H5CN
Oxygen concentration: 1.2 x 10-3

Experimental method: pulsed laser photolysis
Data type: time resolved substrate disappearance; sensitizer triplet absorbance at end-of-pulse

Singlet oxygen acceptor = Rub; meas. phiT(S) = 0.75; lambdaexc = 347 nm. Proportion of T1 quenched by O2 = 1; used epsilonT(S) = 12,000 L mol-1 cm-1 at lambdamax; nDelta = 0.21.

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