Zn(etioporphyrin I) [triplet]

excited state quenched by Hexachlorobenzene
Roy, J.K.; Carroll, F.A.; Whitten, D.G.
J. Am. Chem. Soc. 96: 6349-55 (1974)

Zn(etioporphyrin I) [triplet] quenched by Hexachlorobenzene at conc. (1-50) x 10–5 mol L–1
Solvent : Benzene, 25ºC

kq = 6.7 x 107(L mol–1 s–1)
Activation energy = 6.3 (20-78ºC)(kJ mol–1)
Entropy of activation = –88(J K–1 mol–1)

Mechanism: exciplex formation
Experimental methods: conventional flash, absorption, single shot signal
Comments: tau increases at higher [Q]

Renge, I.V.; Kuz'min, V.A.; Mironov, A.F.; Borisevich, Yu.E.
Dokl. Phys. Chem. 263(1-3): 181-4 (1982)

Zn(etioporphyrin I) [triplet] quenched by Hexachlorobenzene
Solvent : Benzene, 25ºC

kq <=5 x 103(L mol–1 s–1)


Experimental methods: conventional flash, absorption, single shot signal
Comments: see also 85E593

back...