'Quenching of Excited States of Metal Complexes

UO₂²⁺

excited state quenched by Sn[CH(CH₃)CH₂CH₃]₄

Ambrosz, H.B.; Butter, K.R.; Kemp, T.J.
Faraday Discuss. Chem. Soc. : 107-19 (1984)

UO₂²⁺ quenched by Sn[CH(CH₃)CH₂CH₃]₄
Solvent : Acetone

k_q = 3.0 x 10⁹(L mol^–1 s^–1)

Mechanism: reductive electron transfer
Experimental methods: laser flash, luminescence, single shot signal
Comments: S as ClO₄^– salt