'Quenching of Excited States of Metal Complexes

UO₂²⁺

excited state quenched by Ni(CO)₄

Sostero, S.; Traverso, O.; Di Bernardo, P.; Kemp, T.J.
J. Chem. Soc., Dalton Trans. : 658-60 (1979)

UO₂²⁺ quenched by Ni(CO)₄
Solvent : Acetone or Acetonitrile or THF

k_q = 1.6 x 10⁸(L mol^–1 s^–1)

Mechanism: reductive electron transfer
Experimental methods: laser flash, luminescence, , luminescence
Comments: S as NO₃^– salt