Tb3+ [5D4]

excited state quenched by 2-Acetylnaphthalene

Ermolaev, V.L.; Tachin, V.S.
Theor. Exp. Chem. (Engl. Transl.) 9: 432-4 (1973)

Tb3+ [5D4] quenched by 2-Acetylnaphthalene
Solvent : 1-PrOH

kq = 1.2 x 106(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air saturated = 1140 micro sec.


Ermolaev, V.L.; Tachin, V.S.
Theor. Exp. Chem. (Engl. Transl.) 9: 432-4 (1973)

Tb3+ [5D4] quenched by 2-Acetylnaphthalene
Solvent : Acetonitrile

kq = 1.5 x 107(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air saturated = 930 micro sec.


Ermolaev, V.L.; Tachin, V.S.
Opt. Spectrosc. (USSR) 29: 49-52 (1970)

Tb3+ [5D4] quenched by 2-Acetylnaphthalene at conc. <= 0.005 mol L–1
Solvent : Acetone, 20ºC

kq = 2.1 x 106(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, , luminescence
Lifetime in the absence of quencher, air free = 1000 micro sec.
This value also reported in 73F674


Ermolaev, V.L.; Tachin, V.S.
Theor. Exp. Chem. (Engl. Transl.) 9: 432-4 (1973)

Tb3+ [5D4] quenched by 2-Acetylnaphthalene
Solvent : DMF

kq = 3.0 x 105(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air saturated = 1400 micro sec.


Ermolaev, V.L.; Tachin, V.S.
Theor. Exp. Chem. (Engl. Transl.) 9: 432-4 (1973)

Tb3+ [5D4] quenched by 2-Acetylnaphthalene
Solvent : DMSO

kq = 7.1 x 104(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air saturated = 2100 micro sec.


Ermolaev, V.L.; Tachin, V.S.
Theor. Exp. Chem. (Engl. Transl.) 9: 432-4 (1973)

Tb3+ [5D4] quenched by 2-Acetylnaphthalene
Solvent : EtOH

kq = 1.1 x 106(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air saturated = 740 micro sec.


Ermolaev, V.L.; Tachin, V.S.
Theor. Exp. Chem. (Engl. Transl.) 9: 432-4 (1973)

Tb3+ [5D4] quenched by 2-Acetylnaphthalene
Solvent : Ethyl acetate

kq = 2.0 x 106(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air saturated = 870 micro sec.


Ermolaev, V.L.; Tachin, V.S.
Theor. Exp. Chem. (Engl. Transl.) 9: 432-4 (1973)

Tb3+ [5D4] quenched by 2-Acetylnaphthalene
Solvent : H2O

kq = 2.0 x 106(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air saturated = 470 micro sec.


Ermolaev, V.L.; Tachin, V.S.
Theor. Exp. Chem. (Engl. Transl.) 9: 432-4 (1973)

Tb3+ [5D4] quenched by 2-Acetylnaphthalene
Solvent : MeOH

kq = 7.0 x 106(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air saturated = 1050 micro sec.


Ermolaev, V.L.; Tachin, V.S.
Theor. Exp. Chem. (Engl. Transl.) 9: 432-4 (1973)

Tb3+ [5D4] quenched by 2-Acetylnaphthalene
Solvent : TBP

kq = 9.0 x 103(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air saturated = 2100 micro sec.


Ermolaev, V.L.; Tachin, V.S.
Theor. Exp. Chem. (Engl. Transl.) 9: 432-4 (1973)

Tb3+ [5D4] quenched by 2-Acetylnaphthalene
Solvent : THF

kq = 5.0 x 109(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air saturated = 410 micro sec.


Ermolaev, V.L.; Tachin, V.S.
Theor. Exp. Chem. (Engl. Transl.) 9: 432-4 (1973)

Tb3+ [5D4] quenched by 2-Acetylnaphthalene
Solvent : Pyridine

kq = 2.0 x 105(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air saturated = 940 micro sec.


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