Tb3+ [5D4]

excited state quenched by Nd3+

Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : (C2H5)2O, 20ºC

kq = 1.7 x 106(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 920 micro sec.


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : 1-PrOH, 20ºC

kq = 7.7 x 104(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 1100 micro sec.
This value also reported in 72E319


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : 2-PrOH, 20ºC

kq = 1.0 x 105(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 1000 micro sec.


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : Acetonitrile, 20ºC

kq = 2.1 x 105(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 930 micro sec.
This value also reported in 72E319


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : Acetaldehyde, 20ºC

kq = 3.3 x 105(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 840 micro sec.


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 26: 415-8 (1969)

Tb3+ [5D4] quenched by Nd3+ at conc. <= 0.025 mol L–1
Solvent : Acetone, 20ºC

kq = 1.2 x 105(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, , luminescence
Lifetime in the absence of quencher, air free = 1060 micro sec.
This value also reported in 68E121


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : Acetophenone, 20ºC

kq = 2.4 x 105(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 620 micro sec.


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : Allyl alcohol, 20ºC

kq = 5.3 x 104(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 1200 micro sec.


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : Benzaldehyde, 20ºC

kq = 7.5 x 105(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 620 micro sec.


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : Benzonitrile, 20ºC

kq > 3.4 x 105(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 750 micro sec.


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : DMA, 20ºC

kq = 4.3 x 104(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 1600 micro sec.


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : DMF, 20ºC

kq = 6.5 x 104(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 1600 micro sec.
This value also reported in 72E319


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : DMSO, 20ºC

kq = 1.0 x 104(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 2200 micro sec.
This value also reported in 72E319


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : EtOH, 20ºC

kq = 3.8 x 104(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 1240 micro sec.
This value also reported in 72E319


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 26: 415-8 (1969)

Tb3+ [5D4] quenched by Nd3+
Solvent : H2O, 20ºC

kq = 4.5 x 103(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, , luminescence
Lifetime in the absence of quencher, air free = 470 micro sec.


Gruzdev, V.P.
Opt. Spectrosc. (USSR) 49: 657-9 (1980)

Tb3+ [5D4] quenched by Nd3+
Solvent : H2O, 22ºC, pH 5.9, ionic strength 0.6

kq = 7 x 103(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: laser flash, luminescence, single shot signal


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : Isoamyl alcohol, 20ºC

kq = 1.3 x 105(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 1100 micro sec.


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : MeOH, 20ºC

kq = 2.4 x 104(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 1350 micro sec.
This value also reported in 72E319


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : TBP/Toluene (2/1), 20ºC

kq = 9.6 x 103(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 2100 micro sec.
This value also reported in 72E319


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : n-Amyl alcohol, 20ºC

kq = 9.8 x 104(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 1250 micro sec.


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : n-BuOH, 20ºC

kq = 1.0 x 105(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 1170 micro sec.


Antipenko, B.M.; Ermolaev, V.L.
Opt. Spectrosc. (USSR) 30: 39-42 (1971)

Tb3+ [5D4] quenched by Nd3+
Solvent : Pyridine, 20ºC

kq = 1.6 x 104(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 970 micro sec.
This value also reported in 72E319


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