Tb3+ [5D3]

excited state quenched by Tb3+
Tokousbalides, P.; Chrysochoos, J.
Chem. Phys. Lett. 29: 226-9 (1974)

Tb3+ [5D3] quenched by Tb3+ at conc. <= ~0.05 mol L–1
Solvent : POCl3/SnCl4 (9/1), –10ºC

kq = 2.2 x 104(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal

Tokousbalides, P.; Chrysochoos, J.
Chem. Phys. Lett. 29: 226-9 (1974)

Tb3+ [5D3] quenched by Tb3+ at conc. <= ~0.05 mol L–1
Solvent : POCl3/SnCl4 (9/1), 25ºC

kq = 3.9 x 104(L mol–1 s–1)
Activation energy = ~12 (–10 to +30ºC)(kJ mol–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal

Tokousbalides, P.; Chrysochoos, J.
Chem. Phys. Lett. 29: 226-9 (1974)

Tb3+ [5D3] quenched by Tb3+ at conc. <= ~0.05 mol L–1
Solvent : POCl3/SnCl4 (9/1), 30ºC

kq = 4.5 x 104(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal

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