Sm3+ excited state quenched by Sm3+

Sm³⁺ quenched by Sm³⁺ at conc. <= 0.2 mol L^–1
Solvent : POCl₃/SnCl₄ (10/1), –10ºC

k_q = 4.6 x 10²(L mol^–1 s^–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 3000 micro sec.
Comments: tau₀ extrap'd to [S] = 0

Sm³⁺ quenched by Sm³⁺ at conc. <= 0.2 mol L^–1
Solvent : POCl₃/SnCl₄ (10/1), 21ºC

k_q = 6.0 x 10²(L mol^–1 s^–1)
Activation energy = 5.4 (–10 to 55ºC)(kJ mol^–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 3000 micro sec.
Comments: tau₀ extrap'd to [S] = 0

Sm³⁺ quenched by Sm³⁺ at conc. <= 0.2 mol L^–1
Solvent : POCl₃/SnCl₄ (10/1), 55ºC

k_q = 8.0 x 10²(L mol^–1 s^–1)

Mechanism: energy transfer
Experimental methods: conventional flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 3000 micro sec.
Comments: tau₀ extrap'd to [S] = 0