Ru(bpy)32+

excited state quenched by N,N'-Dioctyl-vio2+, beta-CD complex
Adar, E.; Degani, Y.; Goren, Z.; Willner, I.
J. Am. Chem. Soc. 108: 4696-700 (1986)

Ru(bpy)32+ quenched by N,N'-Dioctyl-vio2+, beta-CD complex at conc. (5-50) x 10–4 mol L–1
Solvent : H2O, variable [beta-CD]

kq = 8.5 x 108(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Comments: nonlinear Stern-Volmer plots; kq eval'd from kobs at various [beta-Cyclodextrin]

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