Ru(bpy)32+

excited state quenched by N,N'-Dimethyl-bpy2+
Bock, C.R.; Connor, J.A.; Gutierrez, A.R.; Meyer, T.J.; Whitten, D.G.; Sullivan, B.P.; Nagle, J.K.
J. Am. Chem. Soc. 101: 4815-24 (1979)

Ru(bpy)32+ quenched by N,N'-Dimethyl-bpy2+
Solvent : Acetonitrile, 0.1 mol/L TEAP, ~22ºC

kq = 9.1 x 107(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 0.85 micro sec. (767009)

Amouyal, E.; Zidler, B.; Keller, P.; Moradpour, A.
Chem. Phys. Lett. 74: 314-7 (1980)

Ru(bpy)32+ quenched by N,N'-Dimethyl-bpy2+
Solvent : H2O, 0.5 mol/L ACbuf, pH 5

kq = 1.8 x 108(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: laser flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 0.69 micro sec.
This value also reported in 82C019

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