Ru(bpy)32+

excited state quenched by N,N'-Dibenzyl-vio2+
Johansen, O.; Launikonis, A.; Mau, A.W.-H.; Sasse, W.H.F.
Aust. J. Chem. 33: 1643-8 (1980)

Ru(bpy)32+ quenched by N,N'-Dibenzyl-vio2+
Solvent : EtOH, 22ºC

kq = 3.4 x 108(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: laser flash, luminescence, , luminescence
Lifetime in the absence of quencher, air free = 0.90 micro sec.

Creaser, I.I.; Gahan, L.R.; Geue, R.J.; Launikonis, A.; Lay, P.A.; Lydon, J.D.; McCarthy, M.G.; Mau, A.W.-H.; Sargeson, A.M.; Sasse, W.H.F.
Inorg. Chem. 24: 2671-80 (1985)

Ru(bpy)32+ quenched by N,N'-Dibenzyl-vio2+
Solvent : H2O, ACbuf, 20ºC, pH 5, ionic strength 0.1 (NaClO4)

kq = 1.4 x 109(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: laser flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 0.64 micro sec.

Johansen, O.; Launikonis, A.; Mau, A.W.-H.; Sasse, W.H.F.
Aust. J. Chem. 33: 1643-8 (1980)

Ru(bpy)32+ quenched by N,N'-Dibenzyl-vio2+
Solvent : H2O, 22ºC

kq = 8.3 x 108(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: laser flash, luminescence, , luminescence
Lifetime in the absence of quencher, air free = 0.64 micro sec.

Launikonis, A.; Loder, J.W.; Mau, A.W.-H.; Sasse, W.H.F.; Summers, L.A.; Wells, D.
Aust. J. Chem. 35: 1341-55 (1982)

Ru(bpy)32+ quenched by N,N'-Dibenzyl-vio2+
Solvent : H2O, ACbuf, 22ºC, pH 5

kq = 1.5 x 109(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 0.64 micro sec. (80S001)

Creutz, C.; Keller, A.D.; Sutin, N.; Zipp, A.P.
J. Am. Chem. Soc. 104: 3618-27 (1982)

Ru(bpy)32+ quenched by N,N'-Dibenzyl-vio2+ at conc. (3-50) x 10–4 mol L–1
Solvent : H2O, 0.17 mol/L Na2SO4, 25ºC, ionic strength 0.5

kq = 1.8 x 109(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, , luminescence, single shot signal
Lifetime in the absence of quencher, air free = 0.60 micro sec. (766404)

Takuma, K.; Shuto, Y.; Matsuo, T.
Chem. Lett. : 983-6 (1978)

Ru(bpy)32+ quenched by N,N'-Dibenzyl-vio2+ at conc. (2-10) x 10–4 mol L–1
Solvent : H2O

kq = 2.4 x 109(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 0.6 micro sec.

Rodgers, M.A.J.; Becker, J.C.
J. Phys. Chem. 84: 2762-8 (1980)

Ru(bpy)32+ quenched by N,N'-Dibenzyl-vio2+ at conc. <= 0.02 mol L–1
Solvent : H2O, ionic strength 0 (extrap'd)

kq = 4.4 x 108(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: laser flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 0.55 micro sec.

Amouyal, E.; Zidler, B.; Keller, P.; Moradpour, A.
Chem. Phys. Lett. 74: 314-7 (1980)

Ru(bpy)32+ quenched by N,N'-Dibenzyl-vio2+
Solvent : H2O, 0.5 mol/L ACbuf, pH 5

kq = 1.4 x 109(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: laser flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 0.69 micro sec.
This value also reported in 82C019

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