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Ru(bpy)32+excited state quenched by 1,2-Bis(4-pyridyl)ethane | ![]() |
Ru(bpy)32+ quenched by 1,2-Bis(4-pyridyl)ethane
at conc. 0.0020 mol L–1
Solvent : H2O, 0.01 mol/L Pbuf, 25ºC, pH 5.6, ionic strength 0.1 (LiClO4)
kq <=3 x 107(L mol–1 s–1)
Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 0.6 micro sec.
(766404)