Ru(bpy)32+

excited state quenched by 3,5-Bis(tert-butyl)-1,2-benzoquinone
Vlcek, A.,Jr.; Bolletta, F.
Inorg. Chim. Acta 76: L227-L229 (1983)

Ru(bpy)32+ quenched by 3,5-Bis(tert-butyl)-1,2-benzoquinone
Solvent : DMF

kq = 3.4 x 109(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air saturated = 0.20 micro sec. (laser flash, luminescence, multiple shot with signal averaging)

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