Ru(bpy)32+

excited state quenched by Co(CN)5(pyrazinecarboxylato)3–
Toma, H.E.; Creutz, C.
Inorg. Chem. 16: 545-50 (1977)

Ru(bpy)32+ quenched by Co(CN)5(pyrazinecarboxylato)3–
Solvent : H2O, 0.5 mol/L H2SO4, 25ºC

kq = 2.9 x 109(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, , luminescence, multiple shot with signal averaging
Lifetime in the absence of quencher, air free = 0.60 micro sec. (766404)

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