Ru(bpy)32+

excited state quenched by cis-Co(bzac)3
Huang, S.-M.Y.; Gafney, H.D.
J. Phys. Chem. 81: 2602-4 (1977)

Ru(bpy)32+ quenched by cis-Co(bzac)3
Solvent : EtOH/CHCl3 (9/1), 23-24ºC

kq = 1.1 x 109(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 0.79 micro sec. (J.N. Demas, priv. comm.)

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