Ru(5-Brphen)32+

excited state quenched by Co(diAMsarH2)5+
Mok, C.-Y.; Zanella, A.W.; Creutz, C.; Sutin, N.
Inorg. Chem. 23: 2891-7 (1984)

Ru(5-Brphen)32+ quenched by Co(diAMsarH2)5+
Solvent : H2O, 0.1 mol/L HCl, 0.1 mol/L LiCl, 25ºC

kq = 5.9 x 108(L mol–1 s–1)

Mechanism: energy transfer, oxidative electron transfer
Experimental methods: steady state irradiation, , luminescence, multiple shot with signal averaging
Lifetime in the absence of quencher, air free = 1.0 micro sec. (766404)

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