Ru(5-Clphen)32+

excited state quenched by Co(4,7-Me2phen)2+
Krishnan, C.V.; Brunschwig, B.S.; Creutz, C.; Sutin, N.
J. Am. Chem. Soc. 107: 2005-15 (1985)

Ru(5-Clphen)32+ quenched by Co(4,7-Me2phen)2+
Solvent : H2O, 0.05 mol/L Pbuf, 25ºC, pH 6.0, [CoII]/[L] = 4.5

kq = 2.4 x 108(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 0.94 micro sec. (766404)

back...