Ru(5-Clphen)32+

excited state quenched by Co(diAMsar)3+
Mok, C.-Y.; Zanella, A.W.; Creutz, C.; Sutin, N.
Inorg. Chem. 23: 2891-7 (1984)

Ru(5-Clphen)32+ quenched by Co(diAMsar)3+
Solvent : H2O, 0.16 mol/L LiCl, 0.05 mol/L EtMO, 25ºC, pH 7.5

kq = 1.4 x 108(L mol–1 s–1)

Mechanism: energy transfer, oxidative electron transfer
Experimental methods: steady state irradiation, , luminescence, multiple shot with signal averaging
Lifetime in the absence of quencher, air free = 0.94 micro sec. (766404)
Electron transfer fraction of quenching = 0.30 at pH 8.1

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