Ru(5-Clphen)32+

excited state quenched by Os(NH3)5(N2)2+
Creutz, C.; Keller, A.D.; Sutin, N.; Zipp, A.P.
J. Am. Chem. Soc. 104: 3618-27 (1982)

Ru(5-Clphen)32+ quenched by Os(NH3)5(N2)2+ at conc. (3-200) x 10–4 mol L–1
Solvent : H2O, 0.5 mol/L H2SO4, 25ºC

kq = 5.2 x 108(L mol–1 s–1)

Mechanism: reductive electron transfer
Experimental methods: steady state irradiation, , luminescence, single shot signal
Lifetime in the absence of quencher, air free = 0.94 micro sec. (766404)

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