Ru(5-Clphen)32+

excited state quenched by Eu3+
Lin, C-T.; Boettcher, W.; Chou, M.; Creutz, C.; Sutin, N.
J. Am. Chem. Soc. 98: 6536-44 (1976)

Ru(5-Clphen)32+ quenched by Eu3+
Solvent : H2O, 0.025 mol/L HCl, [MgCl2] + [Eu3+] = 0.9 mol/L, 25ºC

kq <=5 x 104(L mol–1 s–1)


Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 0.94 micro sec. (laser flash, luminescence, multiple shot with signal averaging)
Comments: Q mainly as EuCl2+

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