Ru(5-Clphen)32+

excited state quenched by Co(sep)3+
Mok, C.-Y.; Zanella, A.W.; Creutz, C.; Sutin, N.
Inorg. Chem. 23: 2891-7 (1984)

Ru(5-Clphen)32+ quenched by Co(sep)3+
Solvent : H2O, 0.2 mol/L LiCl, 25ºC

kq = 2.7 x 108(L mol–1 s–1)

Mechanism: energy transfer, oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 0.94 micro sec. (766404)
Electron transfer fraction of quenching = 0.35

Mok, C.-Y.; Zanella, A.W.; Creutz, C.; Sutin, N.
Inorg. Chem. 23: 2891-7 (1984)

Ru(5-Clphen)32+ quenched by Co(sep)3+
Solvent : H2O, 0.5 mol/L H2SO4, 25ºC

kq = 2.0 x 108(L mol–1 s–1)

Mechanism: energy transfer, oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 0.94 micro sec. (766404)

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