Ru(5-Clphen)32+

excited state quenched by Co(NH3)63+
Zahir, K.; Boettcher, W.; Haim, A.
Inorg. Chem. 24: 1966-8 (1985)

Ru(5-Clphen)32+ quenched by Co(NH3)63+ at conc. (3-90) x 10–4 mol L–1
Solvent : H2O, ACbuf, 25ºC, pH 4.7, ionic strength 0.01 (NaCl)

kq = 3.2 x 107(L mol–1 s–1)

Mechanism: energy transfer, oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 0.94 micro sec. (84A238)

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