Rh(NH3)5I2+

excited state quenched by OH–
Frink, M.E.; Magde, D.; Sexton, D.; Ford, P.C.
Inorg. Chem. 23: 1238-40, 2728 (1984)

Rh(NH3)5I2+ quenched by OH–
Solvent : H2O, 25ºC

kq = 1.9 x 1010(L mol–1 s–1)

Mechanism: proton transfer
Experimental methods: laser flash, luminescence, single photon counting
Lifetime in the absence of quencher, air free = 0.0013 micro sec.
Comments: tau0 at pH 3

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