Rh(NH3)5Cl2+

excited state quenched by CO32–
Adamson, A.W.; Fukuda, R.C.; Larson, M.; Maecke, H.; Puaux, J.P.
Inorg. Chim. Acta 44: L13-L15 (1980)

Rh(NH3)5Cl2+ quenched by CO32– at conc. <= 0.005 mol L–1
Solvent : H2O, CAbuf, 4ºC, pH 10.1

kq = 8.3 x 109(L mol–1 s–1)

Mechanism: proton transfer
Experimental methods: steady state irradiation, , luminescence, single shot signal
Lifetime in the absence of quencher, unknown oxygen content = 0.0301 micro sec.

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