Rh(NH3)5Br2+

excited state quenched by OH

Larson, M.; Maecke, H.; Rumfeldt, R.C.; Adamson, A.W.
Inorg. Chim. Acta 57: 229-35 (1982)

Rh(NH3)5Br2+ quenched by OH
Solvent : H2O, 5ºC

kq = 2.7 x 1010(L mol–1 s–1)

Mechanism: proton transfer
Experimental methods: steady state irradiation, , , luminescence, single shot signal
Lifetime in the absence of quencher, air free = 0.0241 micro sec.
Comments: see Mech. [5]


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