'Quenching of Excited States of Metal Complexes

Rh(ND₃)₅Cl²⁺

excited state quenched by OH^–

Larson, M.; Maecke, H.; Rumfeldt, R.C.; Adamson, A.W.
Inorg. Chim. Acta 57: 229-35 (1982)

Rh(ND₃)₅Cl²⁺ quenched by OH^–
Solvent : H₂O, 5ºC

k_q = 8.1 x 10⁹(L mol^–1 s^–1)

Mechanism: proton transfer
Experimental methods: steady state irradiation, , luminescence, single shot signal