cis-Rh(phen)2Cl2+

excited state quenched by 1,2,4-Trimethoxybenzene
Ohno, T.
Coord. Chem. Rev. 64: 311-20 (1985)

cis-Rh(phen)2Cl2+ quenched by 1,2,4-Trimethoxybenzene
Solvent : Acetonitrile

kq = 4.1 x 108(L mol–1 s–1)

Mechanism: reductive electron transfer
Experimental methods: laser flash, absorption, single shot signal
Lifetime in the absence of quencher, air free = 0.70 micro sec.
Electron transfer fraction of quenching = 0.065

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