Rh2(1,3-diisocyanopropane)42+ [triplet]

excited state quenched by N-Methylnicotinamide
Milder, S.J.; Goldbeck, R.A.; Kliger, D.S.; Gray, H.B.
J. Am. Chem. Soc. 102: 6761-4 (1980)

Rh2(1,3-diisocyanopropane)42+ [triplet] quenched by N-Methylnicotinamide
Solvent : Acetonitrile, 21ºC, ionic strength 0.0067 (TBAS)

kq = 6.3 x 108(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: laser flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 8.5 micro sec.

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